Distribución de Mg en conchas de Crassostrea gigasControl microestructural y correlaciones cristaloquímicas

  1. Ibisate Diez-Caballero, Ruth
  2. Pizarro Sanz, José Luis
Revista:
Geogaceta

ISSN: 0213-683X

Año de publicación: 2008

Número: 45

Páginas: 95-98

Tipo: Artículo

Otras publicaciones en: Geogaceta

Resumen

The realization of geochemical studies on the right valve of Crassostrea gigas´s shells has allowed demonstrating a microestructural control on the concentration of Mg. The transects studied in this work show that the ratio Mg/Ca is higher in the Prismatic (SP) and Chalk microstructures than in the Regular Foliated (RF) one. The faster precipitation of SP and Chalk could be the reason for the behaviour of the Mg. The unit cell parameters of the principal microstructures in a C. gigas valve have been determined, looking for good correlation between the content of Mg (ppm) and the volume of the unit cell. The presence of Mg2+ (ionic radius=0.65 Å) instead of Ca2+ (ionic radius=0.99 Å), generate an important lattice distortion along the c-axis, allowing the presence of another cations, such as Na+(ionic radius=0.96 Å).